Effect of chemically induced fracturing on the ice nucleation activity of alkali feldspar

Kiselev, Alexei A.; Keinert, Alice; Gaedeke, Tilia; Leisner, Thomas; Sutter, Christoph; Petrishcheva, Elena; Abart, Rainer

Feldspar is an important constituent of airborne mineral dust. Some alkali feldspars exhibit particularly high ice nucleation (IN) activity. This has been related to structural similarities of the ice (10inline-formula M1inlinescrollmathml true normal 1 normal ‾ 8pt13ptsvg-formulamathimgd92faf77c9ef5095febf79d78cead898 acp-21-11801-2021-ie00001.svg8pt13ptacp-21-11801-2021-ie00001.png 0) prism planes and the (100) planes of alkali feldspar. Here the effect of generating feldspar surfaces with close to (100) orientation by means of chemically induced fracturing on the IN activity of alkali feldspar was investigated experimentally. To this end, gem-quality K-rich alkali feldspar was shifted towards more Na-rich compositions by cation exchange with an NaCl–KCl salt melt at 850 inline-formulaC. By this procedure, a system of parallel cracks with an orientation close to the (100) plane of the feldspar was induced. Droplet-freezing assay experiments performed on grain mounts of the cation-exchanged alkali feldspars revealed an increase in the overall density of ice-nucleating active site (INAS) density with respect to the untreated feldspar. In addition, annealing at 550 inline-formulaC subsequent to primary cation exchange further enhanced the INAS density and led to IN activity at exceptionally high temperatures. Although very efficient in experiment, fracturing by cation exchange with an alkali halide salt is unlikely to be of relevance in the conditioning of alkali feldspars in nature. However, parting planes with similar orientation as the chemically induced cracks may be generated in lamellar microstructures resulting from the exsolution of initially homogeneous alkali feldspar, a widespread phenomenon in natural alkali feldspar known as perthite formation. Perthitic alkali feldspars indeed show the highest IN activity. We tentatively ascribe this phenomenon to the preferential exposure of feldspar crystal surfaces oriented sub-parallel to (100).

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Kiselev, Alexei A. / Keinert, Alice / Gaedeke, Tilia / et al: Effect of chemically induced fracturing on the ice nucleation activity of alkali feldspar. 2021. Copernicus Publications.

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