Organic tracers of fine aerosol particles in central Alaska: summertime composition and sources
PM2.5 aerosols were collected at Fairbanks (64.51∘ N and
147.51∘ W) in central Alaska during the summer of 2009 and
analyzed for organic tracer compounds using a gas chromatograph–mass
spectrometer. The organic compounds were grouped into 14 classes based
on their functional groups and sources. Concentrations of the total organics
measured ranged from 113 to 1664 ng m−3 (avg 535 ng m−3).
Anhydrosugars (avg 186 ng m−3) and n-alkanoic acids (avg 185 ng m−3) were 2 major classes among the 14 compound classes. The similar
temporal trends and strong positive correlations among anhydrosugars and
n-alkanoic acids demonstrated that biomass burning (BB) is the major source
of organic aerosols (OAs) in central Alaska. The dominance of higher
molecular weight n-alkanoic acids over lower molecular weight homologs and their carbon preference index (5.6–9.8) confirmed that they were mostly
emitted from plant waxes during BB in central Alaska. The mass concentration
ratios of levoglucosan to mannosan denoted that softwood is the main biomass
burned. The rainfall event distinctly enhanced the levels of mannitol and
arabitol due to the growth of fungi and active discharge of fungal spores in
the subarctic region. Molecular compositions of biogenic secondary organic
aerosol (BSOA) tracers inferred that isoprene is a crucial precursor of BSOA
over central Alaska. Our results suggest forest fires and plant emissions to
be the crucial factors controlling the levels and molecular composition of
OAs in central Alaska. We propose that PM2.5 laden with OAs derived in
central Alaska may significantly impact the air quality and climate in
the Arctic via long-range atmospheric transport.
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