Latitudinal differences in the amplitude of the OAE-2 carbon isotopic excursion: pCO 2 and paleo productivity

van Bentum, E. C.; Reichart, G.-J.; Forster, A.; Sinninghe Damsté, J. S.

A complete, well-preserved record of the Cenomanian/Turonian (C/T) Oceanic Anoxic Event 2 (OAE-2) was recovered from Demerara Rise in the southern North Atlantic Ocean (ODP site 1260). Across this interval, we determined changes in the stable carbon isotopic composition of sulfur-bound phytane (δ 13C phytane), a biomarker for photosynthetic algae. The δ 13C phytane record shows a positive excursion at the onset of the OAE-2 interval, with an unusually large amplitude (~7‰) compared to existing C/T proto-North Atlantic δ 13C phytane records (3–6‰). Overall, the amplitude of the excursion of δ 13C phytane decreases with latitude. Using reconstructed sea surface temperature (SST) gradients for the proto-North Atlantic, we investigated environmental factors influencing the latitudinal δ 13C phytane gradient. The observed gradient is best explained by high productivity at DSDP Site 367 and Tarfaya basin before OAE-2, which changed in overall high productivity throughout the proto-North Atlantic during OAE-2. During OAE-2, productivity at site 1260 and 603B was thus more comparable to the mid-latitude sites. Using these constraints as well as the SST and δ 13C phytane-records from Site 1260, we subsequently reconstructed pCO 2 levels across the OAE-2 interval. Accordingly, pCO 2 decreased from ca. 1750 to 900 ppm during OAE-2, consistent with enhanced organic matter burial resulting in lowering pCO 2. Whereas the onset of OAE-2 coincided with increased pCO 2, in line with a volcanic trigger for this event, the observed cooling within OAE-2 probably resulted from CO 2 sequestration in black shales outcompeting CO 2 input into the atmosphere. Together these results show that the ice-free Cretaceous world was sensitive to changes in pCO 2 related to perturbations of the global carbon cycle.

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van Bentum, E. C. / Reichart, G.-J. / Forster, A. / et al: Latitudinal differences in the amplitude of the OAE-2 carbon isotopic excursion: pCO2 and paleo productivity. 2012. Copernicus Publications.

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