Tropospheric CH 4 signals as observed by NDACC FTIR at globally distributed sites and comparison to GAW surface in situ measurements

Sepúlveda, E.; Schneider, M.; Hase, F.; Barthlott, S.; Dubravica, D.; García, O. E.; Gomez-Pelaez, A.; González, Y.; Guerra, J. C.; Gisi, M.; Kohlhepp, R.; Dohe, S.; Blumenstock, T.; Strong, K.; Weaver, D.; Palm, M.; Sadeghi, A.; Deutscher, N. M.; Warneke, T.; Notholt, J.; Jones, N.; Griffith, D. W. T.; Smale, D.; Brailsford, G. W.; Robinson, J.; Meinhardt, F.; Steinbacher, M.; Aalto, T.; Worthy, D.

We present lower/middle tropospheric column-averaged CH 4 mole fraction time series measured by nine globally distributed ground-based FTIR (Fourier transform infrared) remote sensing experiments of the Network for the Detection of Atmospheric Composition Change (NDACC). We show that these data are well representative of the tropospheric regional-scale CH 4 signal, largely independent of the local surface small-scale signals, and only weakly dependent on upper tropospheric/lower stratospheric (UTLS) CH 4 variations. In order to achieve the weak dependency on the UTLS, we use an a posteriori correction method. We estimate a typical precision for daily mean values of about 0.5% and a systematic error of about 2.5%. The theoretical assessments are complemented by an extensive empirical study. For this purpose, we use surface in situ CH 4 measurements made within the Global Atmosphere Watch (GAW) network and compare them to the remote sensing data. We briefly discuss different filter methods for removing the local small-scale signals from the surface in situ data sets in order to obtain the in situ regional-scale signals. We find good agreement between the filtered in situ and the remote sensing data. The agreement is consistent for a variety of timescales that are interesting for CH 4 source/sink research: day-to-day, monthly, and inter-annual. The comparison study confirms our theoretical estimations and proves that the NDACC FTIR measurements can provide valuable data for investigating the cycle of CH 4.



Sepúlveda, E. / Schneider, M. / Hase, F. / et al: Tropospheric CH4 signals as observed by NDACC FTIR at globally distributed sites and comparison to GAW surface in situ measurements. 2014. Copernicus Publications.


12 Monate:

Grafik öffnen


Rechteinhaber: E. Sepúlveda et al.

Nutzung und Vervielfältigung: