Aerosol-deposited BaFe 0.7Ta 0.3O 3-δ for nitrogen monoxide and temperature-independent oxygen sensing

Bektas, M.; Hanft, D.; Schönauer-Kamin, D.; Stöcker, T.; Hagen, G.; Moos, R.

The gas sensing properties of resistive gas sensors of BaFe 0.7Ta 0.3O 3-δ (BFT30) prepared by the so-called aerosol deposition method, a method to manufacture dense ceramic films at room temperature, were investigated. The electrical response of the films was investigated first under various oxygen concentrations and in a wide temperature range between 350 and 900 °C. Between 700 and 900 °C, the conductivity of BaFe 0.7Ta 0.3O 3-δ (BFT30) depends on the oxygen concentration with a slope of almost 1/4 in the double-logarithmic plot vs. oxygen partial pressure. In addition, the sensor response is temperature independent. BFT30 responds fast and reproducibly to changing oxygen partial pressures even at 350 °C. The cross-sensitivity has been investigated in environments with various gases (C 3H 8, NO, NO 2, H 2, CO, CO 2, and H 2O) in synthetic air between 350 and 800 °C. BFT30 exhibits good sensing properties to NO between 350 and 400 °C in the range from 1.5 to 2000 ppm with a high selectivity to the other investigated gas species. Thus this semiconducting ceramic material is a good candidate for a temperature-independent oxygen sensor at high temperatures with the application in exhausts and for a selective nitrogen monoxide (NO) sensor at low temperatures for air quality monitoring.

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Bektas, M. / Hanft, D. / Schönauer-Kamin, D. / et al: Aerosol-deposited BaFe0.7Ta0.3O3-δ for nitrogen monoxide and temperature-independent oxygen sensing. 2014. Copernicus Publications.

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