The role of chlorine in global tropospheric chemistry

Wang, Xuan; Jacob, Daniel J.; Eastham, Sebastian D.; Sulprizio, Melissa P.; Zhu, Lei; Chen, Qianjie; Alexander, Becky; Sherwen, Tomás; Evans, Mathew J.; Lee, Ben H.; Haskins, Jessica D.; Lopez-Hilfiker, Felipe D.; Thornton, Joel A.; Huey, Gregory L.; Liao, Hong

We present a comprehensive simulation of tropospheric chlorine within the GEOS-Chem global 3-D model of oxidant–aerosol–halogen atmospheric chemistry. The simulation includes explicit accounting of chloride mobilization from sea salt aerosol by acid displacement of HCl and by other heterogeneous processes. Additional small sources of tropospheric chlorine (combustion, organochlorines, transport from stratosphere) are also included. Reactive gas-phase chlorine Clinline-formula*, including Cl, ClO, inline-formulaCl2, BrCl, ICl, HOCl, inline-formulaClNO3, inline-formulaClNO2, and minor species, is produced by the inline-formulaHCl+OH reaction and by heterogeneous conversion of sea salt aerosol chloride to BrCl, inline-formulaClNO2, inline-formulaCl2, and ICl. The model successfully simulates the observed mixing ratios of HCl in marine air (highest at northern midlatitudes) and the associated inline-formulaHNO3 decrease from acid displacement. It captures the high inline-formulaClNO2 mixing ratios observed in continental surface air at night and attributes the chlorine to HCl volatilized from sea salt aerosol and transported inland following uptake by fine aerosol. The model successfully simulates the vertical profiles of HCl measured from aircraft, where enhancements in the continental boundary layer can again be largely explained by transport inland of the marine source. It does not reproduce the boundary layer inline-formulaCl2 mixing ratios measured in the WINTER aircraft campaign (1–5 ppt in the daytime, low at night); the model is too high at night, which could be due to uncertainty in the rate of the inline-formula M11inlinescrollmathml chem normal ClNO normal 2 + normal Cl - 62pt14ptsvg-formulamathimgdf983f5d64d41ca8dd3748b9c08f7ae2 acp-19-3981-2019-ie00001.svg62pt14ptacp-19-3981-2019-ie00001.png reaction, but we have no explanation for the high observed inline-formulaCl2 in daytime. The global mean tropospheric concentration of Cl atoms in the model is 620 cminline-formula−3 and contributes 1.0 % of the global oxidation of methane, 20 % of ethane, 14 % of propane, and 4 % of methanol. Chlorine chemistry increases global mean tropospheric BrO by 85 %, mainly through the inline-formula M14inlinescrollmathml chem normal HOBr + normal Cl - 58pt12ptsvg-formulamathimg813fc4a530245e7624a6bb6e43294191 acp-19-3981-2019-ie00002.svg58pt12ptacp-19-3981-2019-ie00002.png reaction, and decreases global burdens of tropospheric ozone by 7 % and OH by 3 % through the associated bromine radical chemistry. inline-formulaClNO2 chemistry drives increases in ozone of up to 8 ppb over polluted continents in winter.

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Wang, Xuan / Jacob, Daniel J. / Eastham, Sebastian D. / et al: The role of chlorine in global tropospheric chemistry. 2019. Copernicus Publications.

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